Advancing the Study and Treatment of Water Contaminants

Using chemistry and natural processes to remove harmful chemicals from water

Drinking water treatment plants remove large particles like dirt, while killing pathogens that can make us sick. Although these processes make the water safer to drink, they are not designed to remove many organic pollutants that are present in low concentrations and can lead to negative health effects when consumed. Dr. Christina Remucal, Assistant Professor of Civil and Environmental Engineering at University of Wisconsin-Madison, is using fundamental chemistry to study contaminant transformation, photochemistry, and reactive oxidant production in both engineered (drinking water treatment) and natural (lakes/rivers) systems. As she researches the fate of chemicals in the aquatic environment, she aims to develop new ways to remove chemicals from drinking water through natural processes.

Common water contaminants include pesticides added to fields or urban environments, and pharmaceuticals and personal care products that pass through us to wastewater treatment plants, ending up in the environment. With her team of chemists and engineers, as well as collaborations with colleagues, Dr. Remucal’s research includes extensive study about what happens when these chemicals end up in our water. In a natural environment, such as a lake or river, they explore how fast degradation happens through reaction with sunlight, and whether or not the contaminants turn into less toxic compounds when they degrade. Concerning drinking water, she and her team are investigating new ways to degrade chemicals that are not removed well by conventional drinking water treatment processes. These chemicals include endocrine-disrupting compounds, which can turn male fish into female fish, and are bioactive at the same levels found in the environment. Some of these novel water treatment processes can also be used in developing countries to disinfect water at the household level, potentially providing safer water to millions of people that do not have access to it. 

Current projects include:

The formation of disinfection by products during chlorine photolysis - Dr. Remucal and her team are studying a new water treatment application that takes advantage of the existing drinking water infrastructure to remove contaminants and chlorine-resistant pathogens by shining light on chlorine disinfection units. With her research into this advanced drinking water treatment system, Dr. Remucal is not only investigating the fundamental chemistry processes involved in contaminant removal, but exploring how the formation of disinfection by-products changes. These potentially cancer-causing products are formed when chlorine, the most common water disinfectant in the U.S., is used to kill pathogens in water. Understanding the formation of disinfection by-products is critical to the safety of the new drinking water treatment process. In addition, this new water system can also be used as a point-of-use treatment application in developing countries, where millions of people lack access to safe drinking water. One way an individual may treat their water is through solar disinfection, which involves putting water in plastic bottles and placing it in the sun. Dr. Remucal’s research could speed up this sunlight-based water treatment process, making it more reliable for people that depend on it to keep their water safe to drink. 

Photodegradation of pesticides used to kill invasive species - The sea lamprey—a parasitic fish that feeds on large fish—has been an environmental problem for the past 60 years. The main method used to kill these invasive creatures is by directly adding two pesticides into the rivers in which they reside. Dr. Remucal is studying what happens when these toxic chemicals come in contact with sunlight, how quickly they degrade and which products they form. Dr. Remucal collaborates with governmental agencies and her work will directly affect environmental policy. 

Manganese oxides for contaminant removal - Found in the soil, these naturally occurring minerals can be used to degrade certain pollutants. Because they are naturally highly active, Dr. Remucal posed the question, “Can we use these minerals to remove contaminants from stormwater?” When it rains, the rainwater picks up everything in its path, such as pesticides from lawns and chemicals on cars, and often flows straight into a lake or river. Dr. Remucal and her team are investigating ways to direct stormwater through green infrastructure, such as a manganese oxide-based reactive infiltration systems, reducing contaminant loads before the runoff hits surface water. 

Bio

Dr. Christina Remucal’s interest in water evolved while growing up in a ski town in the desert of northern New Mexico. Her hometown heavily relies on the efficient use of scarce water resources, giving Dr. Remucal a huge appreciation for the importance of water. With her love of science and math, Dr. Remucal decided to attend Massachusetts Institute of Technology (MIT) as an undergraduate. It was there that she first discovered the field of environmental engineering. She was drawn to the field because it combines chemistry, biology, math, and physics to solve important problems, such as purifying drinking water. She also liked that it allowed her to go outside, for activities like field sampling.

Dr. Remucal completed her postdoctoral research at the Institute of Biogeochemistry and Pollutant Dynamics at Swiss Federal Institute of Technology from 2009 to 2012. She currently serves as Assistant Professor in the Department of Civil and Environmental Engineering, and is also affiliated with the Environmental Chemistry and Technology Program, the Freshwater and Marine Science Program, and the Molecular and Environmental Toxicology Center.

Dr. Remucal misses the excellent skiing in the southern Rockies but appreciates the beauty of the lakes in the upper Midwest. Living in a water-rich area like Wisconsin, she sees that there are many stressors on the health of our aquatic environment and is motivated to improve the quality of our water resources. 

In the News

From a Water Nuisance to a Water Cleanser

Water Resources Institute Project Looks at Manganese in the Madison Water System

Publications

Enhanced indirect photochemical transformation of histidine and histamine through association with chromophoric dissolved...

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A critical review of the reactivity of manganese oxides with organic contaminants.

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The role of indirect photochemical degradation in the environmental fate of pesticides: A review.

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Low molecular weight components in an aquatic humic substance as characterized by membrane dialysis and Orbitrap mass...

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Photosensitized amino acid degradation in the presence of riboflavin and its derivatives.

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The role of iron coordination in the production of reactive oxidants from ferrous iron oxidation by oxygen and hydrogen...

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Oxidative stress induced by zero-valent iron nanoparticles and Fe(II) in human bronchial epithelial cells.

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Ligand-enhanced reactive oxidant generation by nanoparticulate zero-valent iron and oxygen.

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Awards

NSF CAREER Award, 2015

ESPI HOT Article; Among top 20 most downloaded articles in 2014

2014 Remucal C.K., The role of indirect photochemical degradation in the environmental fate of pesticides: A review. 2014. Environ. Sci. Process. Impacts. 16 (4), 628 – 653

ETH Postdoctoral Fellowship, 2010

Project: Enhancement of visible-light solar water disinfection with riboflavin and its derivatives

U. C. Berkeley Outstanding Graduate Student Instructor Award, 2008

American Chemical Society Division of Environmental Chemistry Graduate Student Paper Award, 2008

Paper: Factors affecting the yield of oxidants from the reaction of nanoparticulate zero-valent iron and oxygen

National Science Foundation Graduate Research Fellowship, 2003